Can't say i've been in the position to do this to a Sierra.... If i recall they have a tie rod so adjustment could be achieved there.
Well I think the front wheel location is achieved by the ARB that locates into the track control arm. If you were to put some sort of shim/spacer at the back interface of the TCA and the ARB it would effectively push the front wheel forward slightly in the arch ( the ARB is mounted behind the TCAs ). I guess this would be useful to equalise caster from one side to the other although I don't know the effect of differing settings on one side compared to the other.