Update:
At the time of my first post I had just come back from driving in France and previously had just had new replacement Goodyears on the front and there were nearly new Kumho KU39's on rear, which was how I bought the car.
In France, however, I had inadvertently driven over a high kerb and back in UK I discovered a deep cut in one of the rear Kumhos and was about to have two new Goodyears on the rear. This has now been done with Hunter realignment and the car drives a lot better and seems more composed on motorway. I kept the settings similar to previous with just a touch less rear camber @ -1deg 17min ea side.
There is definitely a better ride with the Goodyears on rear too and it makes me think there was an incompatibiity between the Kumhos and the Goodyears.
The technician commented on the "large amount of rear camber" and did I want to reduce it further. Is there a case for reducing camber when doing mainly motorway miles? I just got back from a 15 mile fast motorway run and the temperature of the inside tread band felt a little warmer than the rest of the tread but I guess this isn`t unusual.